Antimony
Antimony is a brittle metal, silvery gray in color. It has the property of expanding upon freezing, and its main application has been as a constituent of type metal (82% lead, 15% antimony, 3% tin). The expansion upon solidifying gives sharp reproduction of type characters in the molds. Antimony is also used as a constituent of other alloys for uses like the grids in storage batteries and for bearings. One mineral source of antimony is stibnite. Antimony oxide, Sb2O3, forms the minerals valentinite and senarmontite. Stibarsen, SbAs, is a silvery mineral with a metallic luster. Antimony forms the sulfide kermesite, Sb2OS2. Antimony forms a sulfide with lead and iron called Jamesonite. A sulfide of antimony along with copper and iron is called tetrahedrite. A sulfide with iron forms the mineral berthierite and with copper the mineral chalcostibite, CuSbS2. Antimony forms sulfides with lead called zinkenite, plagionite, semseyite and boulangerite. It also forms sulfides with silver called Stephanite, miargyrite and pyrargyrite. The sulfide formed with nickel is called ullmannite. A sulfide formed with lead and arsenic is called jordanite. A sulfide formed with tin, iron and lead is called cylindrite. Bournonite is a sulfide with copper, lead and antimony. Tennantite is a sulfide which contains antimony, copper, iron and arsenic.
Antimony is found in the mineral nagyagite, a sulfide, along with lead, iron, gold, and tellurium. Silver joins with lead and antimony in the sulfide andorite, AgPbSb3S6. In the mineral dyscrasite, silver bonds directly to antimony in the form Ag3Sb.
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Antimony is one of the few elements which can be found in nature in pure form. This sample of antimony is displayed in the Smithsonian Museum of Natural History. The sample is about 4x5 cm and is from Consols mine, Broken Hill, New South Wales, Australia.
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Periodic Table
Chemistry concepts
Reference Pauling Ch. 16, 28 |